Sometimes coolant can flow into the resevoir so fast that it splashes against the side,.. near the cap where the pressure relief valve is.
The little extra bursts of pressure, in addition to normal operating pressure, can cause the valve to pop open and leak coolant.
Not sure if this is the case on the round resevoir seems like it has a divider to block it from splashing on the cap.
I have seen it on the earlier MK2 resevoirs that in the MK1s have the often clogged restrictor in the radiator outlet barb.