in most cases this can be fixed at machine shop with a fresh spot face, find one that is creative, familiar with VW-d's and confident they can do it (and look at some of their equip, and machine work to assure they are not blowing smoke, or get references) It really is not tough to do, but not 'conventional' either. They may need to make up a special tool, but thats not so unusual ... Someone who does lots of vw-D heads will have a cutter for this laying around their tool box.
You want to be sure that there are not ignition craters eroded somewhere. Injectors can shoot a bogus spray, and end up burning a horizontal hole in injector seat area.
Never sieze is not a very good sealant. I like to use a hydraulic fitting sealant for injection issues (but if you have to use a sealant, somethings wrong) the HYD stuff is made to seal 2000 psi., but it is not too high temp.