The only component that it unique to any one cylinder is the delivery valve. Delivery valves are just high pressure check valves. They don't often fail and a failed one would certainly not be noticed when the injection line was loosened and the pressure was relieved.
Is there something else we could try to bleed that one injector line?
Previous owner says that he parked it when it began to get hard to start in the winter.
Wouldn't a bad or stuck check valve allow air to be drawn into the pump chamber on the suction stroke?