on the question of boost affecting valve float:
there is no question that the increased pressure gradient across the valve head will have some effect, detailed nicely in an earlier post, on the float point of your valves.
however, 30lbs of force (about 130N) is probably not a large percentage of the overall spring rate of the valve spring(s).
stiffer valve springs will negate any potential problems with valve float, the stiffer aftermarket gasser ones will work just fine. the issues you may have with this relate to excessive wear of cam lobes and shims. this may or may not be an issue. there are also more mechanical losses incurred within the valve train by using stiffer valve springs, which will at least in some small way, affect power output at all revs.
so, if your not going to use your engine at high revs, stiffer valve springs are not going to be much of an advantage, if any.
lightening the valve train, with titanium/lightened steel retainers, etc, is also a waste of money.
with regard to combustion chamber volumes: it is very important to get them equal. the engine will last so much longer of you do.