yes you are correct , the higher the injector pop pressure the later the injector actucally fires .
the easiest way to keep the same timing while changing the pop pressure is to use a device that clamps onto an injector line and measures the injector " pulse in the line . ( they hook up to a regular timing light ... can't remeber off hand what it is called , i got mine from snap on , but other companies make them now too ) .
anyways pop the timing cover off of the bell housing and mark on the flywheel where the timing light is flashing at ( keep in mind where the mark you just made sits in relationship to the timing mark on the bell housing ) .
now install your "new " higher pop pressure injectors .
now adjust the injection pump so the timing light flashes on the mark on the flywheel you made earlier .
if you did everything right the new injectors will be firing at the same time as the old ones ( but the timing may not be correct , just the same as what you had before )
btw don't waste your time on merc injectors , buy some vw gtd ones instead .... you will be happier later on