Next up would be to pull the head. Tip it up on its side so the intake and exhaust ports are UP. Pour or spray some solvent into the intake and exhaust port of the offending cylinder. If it pours right back out of one of the valves, you have likely found the culprit. If there is only a tiny dribble or no leakage at all, then pull the piston/rod and inspect. With 0 psi something should stand out.
VW heads always have cracks between cylinders valves. If less than the width of a dime they are fine.
The one thing that still nags at me is that bent valves don't ever 'heal' temporarily. You might be chasing a second issue if you get this one sorted.