IF you assembled the head to block correctly-following-torque procedure (sequence of bolts, placement of gasket, etc.), letting the engine sit should not matter....proved you did not do it well and anti-freeze has run into a cylinder or two. We've seen it all here!More than likely, you do not have the fuel pump totally primed (pressure in the lines has to be built up to actually FIRE the injector...not just pess a little out).OR, you could have the inj. pump 180 degrees out.Or, your pump is not put together properly. We weren't there.
Just gotta do THIS: American ladies GOLD in Olympic Hockey!New gasket. You really need to make use of a straightedge. Need to take comparisons in multiple planes....both head and block.Personally, all I ever do is use old head bolts to clean threads and lots of carb cleaner and a blow-ooot of air. It works fine for me. Others will recommend more elaborate.You can't bang the head down onto the gasket as you assemble. You can't wiggle the head around on the gasket either. There could be the off chance the head is internally cracked.
Did you have the cam installed in the head? Did you have any of the pistons at TDC? If yes to both, then there is a good chance you mashed an open valve into the top of a piston and weren't torquing the head down onto the gasket. Instead you were torquing the open valve into a piston and bending the valve in the process.